A 1.2v Iron-Iron Alkaline Cell From Scrounge
This is not a science project. It’s a real, rechargeable, deep-cycle cell you can build from trash. It’s based on the old Edison nickel-iron battery, but simplified to use only iron and rust. No lead, no lithium, no acid.
Nominal voltage is 1.0-1.2V per cell. Put 5 in series for ∼6V, 10 for ∼12V.
Base Concept
1. Anode (-): Clean iron. A plain steel can packed with plain steel wool that’s been heated once in a can to burn off oil – no coating. When discharging, the iron turns to iron hydroxide (rust) and releases electrons.
2. Cathode (+): Rusted iron. Steel wool that you let rust, then packed tight.
3. Electrolyte: Alkaline water that carries ions between them. The electrolyte does not get consumed.
You are just shuttling oxygen between two pieces of steel in different oxidation states.

1. The Anode – The Outer Can
Best option is a standard 15oz steel vegetable can. This is your negative terminal. The can itself IS the battery case and the anode.
Most food cans today have a thin plastic liner inside to prevent corrosion. You must remove it. Easiest scrounge method: hit the inside with a propane torch or throw it in a campfire for 2-3 minutes until the liner smokes and burns off. Dont breathe the fumes! Then quench in water and hit it quickly with sandpaper or steel wool to expose bare shiny steel. An unlined can is what you want.
Options: any steel can, steel box, steel pipe, or even an old ammo can. Avoid aluminum.
2. The Cathode – The Inner Can
This is where your capacity comes from. You need fluffy iron with a ton of surface area, all rusty.
Take cheap steel wool, #0000 or #0. Wet it with salt water, leave it outside for 2-3 days until it is fully orange/brown and crumbly. That’s your active material.
You need to hold it and make electrical contact:
Scrounger’s Gold: Tomato paste can (5.5oz) perforated. Drill or punch with a nail 30-40 tiny holes all over it. Stuff the rusty wool in as TIGHT as you possibly can with a stick. The can itself is your current collector. Just clip your (+) wire directly to the lip. No internal wire needed. This is the cleanest version.
Upgraded: Steel pipe or EMT conduit with holes drilled, stuffed with rust. Will last for years.
Loose wool = high resistance and low capacity. Pack it like you’re packing black powder.
3. The Separator – Tyvek
You must keep the two cans from touching or you get a dead short. You need a material that lets alkaline water through but stops electrons.
Best to worst:
– Tyvek (house wrap / FedEx / USPS envelopes): Perfect. Porous HDPE that KOH can’t dissolve. One layer is enough.
– Non-woven Geotextile Landscape Fabricj: Actually better than Tyvek for long term but probably more difficult to find.
– Non-woven reusable grocery bag, landscape fabric: Works long term.
– Cotton t-shirt, felt, paper towel: Works for weeks but KOH rots it. Good for testing only.
– Avoid: Plastic bags or plastic wrap – they block ions, battery won’t work.
The separator may be right against both cans. No gap needed. Tighter is better.
Wrap the inner tomato can like a burrito with Tyvek, tuck the bottom, tie with string or zip tie. With grid: seal with a clothes iron on low or hair straightener for 3 seconds. Grid-down: heat a butter knife with a lighter and use it like an iron.
4. The Electrolyte
Best: Potassium hydroxide (KOH), 20-30% by weight in water. That’s about 2-3 cups of KOH flakes per liter of water. KOH gives best performance. Sold as soapmaking lye.
Second: Sodium hydroxide (NaOH), same mix ratio. Works, but self-discharges faster. Sold as 100% lye drain cleaner. Make sure label says 100% lye.
In a pinch: You can make sodium hydroxide using washing soda and builder’s lime.
Grid-down: Wood ash lye. Boil hardwood ash in water, filter clear liquid. Weak, but functional at about 30% of KOH capacity. Boil it down to concentrate it.
Mix with distilled water if you have it. Always add lye TO water, never reverse. Wear glasses and gloves – it will burn skin and eyes.
How Much Power?
This size cell – 15oz outer, 5.5oz inner stuffed with ∼50-80g of rusted wool – will realistically give you *3 to 8 Amp-hours at ∼1V.* That’s 3 to 8 watt-hours per can.
Why the range? It depends entirely on how tight you packed the rust and how well you burned off the liner. A loose pack might give 2 Ah, a hydraulic-pressed pack can exceed 10 Ah.
For context: 10 cells in series (a 12V pack) at 5 Ah each = 50 watt-hours. Enough to run LED lights for a night, charge phones, run a radio. Need more? Add more cans in parallel, or use bigger cans – a #10 food service can easily stores 20-30 Ah.
Assembly and Use Basic Cell
1. Take 1.5 pads, wet with salt water, rust 24-48h until fully orange.
2. Burn liner off outer can, sand inside.
3. Perforate inner can, pack tight with roughly 1.5 pads of rusty wool.
4. Wrap inner can tightly with one layer Tyvek 1/2″ above rim. Zip tie it in place.
5. Put 2-3 plastic bottle caps in the bottom of the outer can as standoffs.
6. Drop wrapped inner can into outer.
9. Attach wires – one to outer can (-), one to inner can lip (+).
10. Fill both sides with 20-30% KOH. Pour electrolyte until Tyvek is saturated and level is just below top of inner can, 1/2″ below the rim. Don’t flood over the separator.
11. Optional but highly recommended –
Mineral oil seal:
After you pour the electrolyte, add about 1/8″ (2-3mm) layer of mineral oil, baby oil, or even clean cooking oil on top of the electrolyte in both cans. It will float.keep the wool below the oil line.
It does two critical things: stops water from evaporating, and stops CO₂ from the air getting into the KOH and turning it into potassium carbonate (which kills performance).
Your cell will hold charge way longer and you won’t have to top up water every week. Leave the oil in – ions move under it, it just sits on top as a lid.
This cell meets your minimum requirements. You will read 0.8V to 1.2V immediately.
There are a couple of things that can be done to improve its performance if the materials can be found.
The first and easiest one is to sprinkle 10% graphite or carbon black into the inner can to improve conduction. Grind the leads from 2-3 #2 pencils per pad to a fine powder. Do not use activated charcoal as it is non-conductive.
The second improvement involves coating the cathode (clean steel wool) with iron sulfide (FeS). Two methods to do this:
1. Use lime sulfur: In a plastic bowl outside add 50ml lime sulfur to 150ml water. Soak 1.5 pads clean steel wool for 20-30 min until jet black. Rinse 5 sec, squeeze damp. This is now FeS/Fe.
2. Use yellow gardening sulfur (sulfur soil amendment): Most feed stores have 5lb bags that will outlast you. Or scrape the tips off 100 strike-anywhere matches, that’s sulfur. Take your clean steel wool pad, sprinkle sulfur powder on it like salt, put it in a steel can with a lid and tiny vent, heat to low red heat in your campfire fire for 5-10 min when you are burning off the plastic.
8Fe + S8 -> 8FeS – It goes black instantly. That’s your FeS outer. No liquid needed.
Pack these treated 1.5 pads of FeS/Fe into your outer green bean annulus to balance the iron in the tomato can.
Even without it, plain clean steel wool outer still works, you just lose about 20% efficiency to hydrogen bubbles on charge. It will still cycle.
One last tweak to the electrolyte is possible. Edison added LiOH to his nickel iron batteries.
LiOH per bean can cell:
• 2.5 – 3.5g LiOH.H2O monohydrate
• or 1.5 – 2g anhydrous LiOH
Just use 3g monohydrate per can – that’s 12-15g/L in that small volume.
If you make 1L of electrolyte (250g KOH + 12g LiOH.H2O), that batch will fill upto bean can cells.
Charging:
Charge at 100mA to 1.4V. The FeS will stop H₂ gassing. First cycle will be low capacity, second cycle is full.
If your cell is 5 Ah, charge at 0.5 amps for 10 hours. That’s what C/10 means – capacity divided by 10. For a 5 Ah cell, C/10 = 5 / 10 = 0.5A. A small 10W solar panel can do this. Do not charge above 1.9V.
You can discharge down to 0.6V. Overcharge just makes hydrogen and uses water – top up with a little water if needed.
Two cans, some rust, and an envelope. No moving parts doesn’t get any simpler.



